Cu-Mn oxygen carrier with improved mechanical resistance: Analyzing performance under CLC and CLOU environments

نویسندگان

چکیده

Chemical Looping Combustion process allows combustion of gaseous, liquid or solid fuels with CO2 capture. The oxygen necessary for can be supplied using lattice (CLC) uncoupling (CLOU) mechanisms. present work studies the effects kaolin addition on CuMn carrier behavior CLC and CLOU processes. was prepared by granulation a composition: 27.2 wt% CuO, 52.8 Mn3O4 20 kaolin. Oxygen release rates fluidization were analyzed TGA batch fluidized bed reactor. studied CH4 synthetic biogas in 500 Wth continuous unit 50 h at temperatures up to 930 °C. No agglomeration problems observed. Results found during similar methane combustion. changed mixed oxide chemical composition generating Cu1.2Mn1.8O4 improved significantly mechanical resistance, increasing extrapolated lifetime 19,000 h, 3.6 times over value any Cu based CLC. However, reactivity had an important decrease respect without addition, whose fraction must optimized.

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ژورنال

عنوان ژورنال: Fuel Processing Technology

سال: 2021

ISSN: ['1873-7188', '0378-3820']

DOI: https://doi.org/10.1016/j.fuproc.2021.106819